Wool is a type of wool gathered from the coats of Merino sheep. T While traditional wool is notorious for being itchy, merino wool is one of the softest forms of wool and doesn’t aggravate the skin. This is because of the small diameter of the fine merino fibers, which makes it more flexible and pliable and therefore less itchy. Merino wool is considered a luxurious fiber and is used frequently for socks and outdoor clothing. Merino wool is known for being odor-resistant, moisture-wicking, and breathable.